16 January 2012
Gabriel Ethylenimine Method (Gabriel-Marckwald Ethylenimine Synthesis)
12:03 PM
Formation of ethylenimines (aziridines) by elimination of hydrogen halides from aliphatic vicinal haloamines with alkali. The method can be extended to the preparation of five- and six-membered cyclic amines:
O. C. Dermer, G. E. Ham, Ethylenimine and Other Aziridines (Academic Press, New York, 1969) pp 1-59; R. Bartnik et al., Pol. J. Chem. 53, 537 (1979); K. H. Sunwoo et al., Dyes Pigments 41, 19 (1999).
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